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Nitrogen Kinetic Isotope Effects for the Monoamine Oxidase B-Catalyzed Oxidation of Benzylamine and (1,1-(2)H(2))Benzylamine: Nitrogen Rehybridization and CH Bond Cleavage Are Not Concerted
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry.
2011 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 133, no 32, 12319-12321 p.Article in journal (Refereed) Published
Abstract [en]

Nitrogen kinetic isotope effects for the oxidation of benzylamine and (1,1-(2)H(2))benzylamine by recombinant human monoamine oxidase B show that cleavage of the CH bond is not concerted with rehybridization of the nitrogen atom.

Place, publisher, year, edition, pages
2011. Vol. 133, no 32, 12319-12321 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-159253DOI: 10.1021/ja205629bISI: 000294740000001OAI: oai:DiVA.org:uu-159253DiVA: diva2:443577
Available from: 2011-09-26 Created: 2011-09-26 Last updated: 2017-12-08Bibliographically approved

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