Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes
2008 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 33, 3888-3890 p.Article in journal (Refereed) Published
High enantioselectivities and activities are achieved in the Ir-catalyzed hydrogenation of several unfunctionalized olefins using modular biaryl phosphite-oxazoline ligands from hydroxyl aminoacid derivatives, the presence of a biaryl phosphite group is crucial to this success.
Place, publisher, year, edition, pages
2008. no 33, 3888-3890 p.
reduction, hydrogenation, diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism), polyphenylalkane derivatives, carboxylic acid esters (benzene compounds), alcohols (benzene compounds)
IdentifiersURN: urn:nbn:se:uu:diva-17849DOI: 10.1039/b806891gISI: 000258686400015OAI: oai:DiVA.org:uu-17849DiVA: diva2:45620