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Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Molecular Biomimetics.
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2011 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 47, no 42, 11662-11664 p.Article in journal (Refereed) Published
Abstract [en]

Mononuclear pentacoordinate iron complexes with a free coordination site were prepared as mimics of the distal Fe (Fe(d)) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.

Place, publisher, year, edition, pages
2011. Vol. 47, no 42, 11662-11664 p.
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Natural Sciences
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URN: urn:nbn:se:uu:diva-161774DOI: 10.1039/c1cc14449aISI: 000296020200020OAI: oai:DiVA.org:uu-161774DiVA: diva2:457934
Available from: 2011-11-21 Created: 2011-11-17 Last updated: 2017-12-08Bibliographically approved

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Karnahl, MichaelSantoni, Marie-PierreLomoth, ReinerOtt, Sascha

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