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Electrical modeling of Cu(In,Ga)Se2 cells with ALD-Zn1xMgxO bufferlayers
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Electronics. (Solar Cell Group)
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Electronics. (Solar Cell Group)
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Electronics. (Solar Cell Group)
2012 (English)In: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 111, no 1, 014509-014509 p.Article in journal (Refereed) Published
Abstract [en]

Electrical modeling of Cu(In,Ga)Se2 solar cells with Zn1-xMgxO buffer layers is performed. A number of  different  device  models  are  implemented  and  tested  by  comparing  simulation  results  and measurement data. Room temperature light-soaking and dark-light cross-over behavior as well aslow-temperature characteristics of these cells are studied. The light-soaking improvements in the solarcell  parameters  are  attributed  to  an  increase  in  buffer  donor  density,  due  to  persistent  photoconductivity, that counteracts charged acceptors in the absorber-buffer region. Dark-light JV-curvecross-over is explained by deep acceptor defects with small electron capture cross-section, in thebuffer. Best correspondence to measurements on ZnO and Zn0.83Mg0.17O cells is obtained with models including absorber-buffer interface acceptor states. No wideband-gap surface defect layer is needed to reproduce measurement data.

Place, publisher, year, edition, pages
American Institute of Physics (AIP), 2012. Vol. 111, no 1, 014509-014509 p.
Keyword [en]
CIGS solar cells, electrical modeling, alternative buffer layers, metastabilities
National Category
Other Electrical Engineering, Electronic Engineering, Information Engineering
Research subject
Engineering Science with specialization in Electronics
Identifiers
URN: urn:nbn:se:uu:diva-166753DOI: 10.1063/1.3672813ISI: 000299127200108OAI: oai:DiVA.org:uu-166753DiVA: diva2:477404
Available from: 2012-01-13 Created: 2012-01-13 Last updated: 2017-12-08Bibliographically approved
In thesis
1. Modelling Band Gap Gradients and Cd-free Buffer Layers in Cu(In,Ga)Se2 Solar Cells
Open this publication in new window or tab >>Modelling Band Gap Gradients and Cd-free Buffer Layers in Cu(In,Ga)Se2 Solar Cells
2012 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

A deeper understanding of Cu(In,Ga)Se2 (CIGS) solar cells is important for the further improvement of these devices. This thesis is focused on the use of electrical modelling as a tool for pursuing this aim. Finished devices and individual layers are characterized and the acquired data are used as input in the simulations. Band gap gradients are accounted for when modelling the devices. The thesis is divided into two main parts. One part that treats the influence of cadmium free buffer layers, mainly atomic layer deposited (Zn,Mg)O, on devices and another part in which the result of CIGS absorber layer modifications is studied. Recombination analysis indicates that interface recombination is limitting the open circuit voltage (Voc) in cells with ZnO buffer layers. This recombination path becomes less important when magnesium is introduced into the ZnO giving a positive conduction band offset (CBO) towards the CIGS absorber layer. Light induced persistent photoconductivity (PPC) is demonstrated in (Zn,Mg)O thin films. Device modelling shows that the measured PPC, coupled with a high density of acceptors in the buffer-absorber interface region, can explain light induced metastable efficiency improvement in CIGS solar cells with (Zn,Mg)O buffer layers. It is shown that a thin indium rich layer closest to the buffer does not give any significant impact on the performance of devices dominated by recombination in the CIGS layer. In our cells with CdS buffer the diffusion length in the CIGS layer is the main limitting factor. A thinner CIGS layer improves Voc by reducing recombination. However, for thin enough absorber layers Voc deteriorates due to recombination at the back contact. Interface recombination is a problem in thin devices with Zn(O,S) buffer layers. This recombination path is overshadowed in cells of standard thickness by recombination in the CIGS bulk. Thin cells with Zn(O,S) buffer layers have a higher efficiency than CdS cells with the same absorber thickness.

Place, publisher, year, edition, pages
Uppsala: Acta Universitatis Upsaliensis, 2012. 70 p.
Series
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, ISSN 1651-6214 ; 900
Keyword
CIGS, Thin film solar cells, Electrical modelling, Alternative buffer layers, Gallium gradients, Simulations, Electrical characterization, Metastabilities, Light-soaking, Hall measurements, Persistent photoconductivity
National Category
Other Electrical Engineering, Electronic Engineering, Information Engineering Materials Engineering Physical Sciences
Research subject
Engineering Science with specialization in Electronics
Identifiers
urn:nbn:se:uu:diva-168618 (URN)978-91-554-8280-0 (ISBN)
Public defence
2012-03-30, Polhemssalen, Ångströmlaboratoriet, Lägerhyddsvägen 1, Uppsala, 13:15 (English)
Opponent
Supervisors
Available from: 2012-03-09 Created: 2012-02-13 Last updated: 2013-04-08Bibliographically approved

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Pettersson, JonasEdoff, MarikaPlatzer-Björkman, Charlotte

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