Logo: to the web site of Uppsala University

uu.sePublications from Uppsala University
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Study of oxygen-C compound formation by NEXAFS and RIXS
Show others and affiliations
2001 (English)In: The European Physical Journal D, Vol. 16, no 1-3, p. 357-360Article in journal (Refereed) Published
Abstract [en]

The interaction of oxygen with C60 molecules was studied on a C60 film which had been exposed simultaneously to oxygen and UV-light for 190 hours, producing an approximately C60O1 stoichiometry in the bulk of the sample. C K-edge and O K-edge NEXAFS (using total fluorescence yield detection) and resonant X-ray inelastic scattering (RIXS) spectra from the sample film were measured and the C K-edge data were compared to the spectra from pristine C60 as reference. The C K-edge absorption and emission spectral profiles of the oxygen-doped sample are similar to those of the C60 reference, suggesting that cage breaking of C60 under these conditions, if any, is negligible. However, the redistribution of intensities in the spectra indicates changes in the occupancies of different molecular orbitals, possibly due to changes in electron density upon reaction. Similarities of the O K-edge soft X-ray emission (SXES) spectra to several small oxygen-containing molecules is being discussed in terms of bonding models.

Place, publisher, year, edition, pages
2001. Vol. 16, no 1-3, p. 357-360
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-21053OAI: oai:DiVA.org:uu-21053DiVA, id: diva2:48826
Available from: 2006-12-14 Created: 2006-12-14 Last updated: 2011-01-13

Open Access in DiVA

No full text in DiVA

Authority records

Jansson, Ulf

Search in DiVA

By author/editor
Jansson, Ulf
By organisation
Department of Materials ChemistryInorganic Chemistry
Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 837 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf