uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism.
2004 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 23, 2748-2749 p.Article in journal (Refereed) Published
Abstract [en]

The negligible double kinetic deuterium isotope effect (kHH/kDD = 1.05) in the reaction where [2,3,4,5-Ph4(η5-C4COH)]Ru(CO)2H (2) transfers a hydride and a proton to N-phenyl-[1-(4-methoxyphenyl)ethylidene]amine (4) indicates that no bond to hydrogen is broken or formed in the rate-detg. step. [on SciFinder(R)]

Place, publisher, year, edition, pages
2004. no 23, 2748-2749 p.
Keyword [en]
hydrogen transfer imine hydroxycyclopentadienylruthenium hydride stepwise mechanism
National Category
Natural Sciences
URN: urn:nbn:se:uu:diva-174523DOI: 10.1039/b410698aOAI: oai:DiVA.org:uu-174523DiVA: diva2:527596
CAPLUS AN 2004:1037547(Journal)Available from: 2012-05-21 Created: 2012-05-21 Last updated: 2012-05-21

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Samec, Joseph S. M.
In the same journal
Chemical Communications
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 279 hits
ReferencesLink to record
Permanent link

Direct link