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Efficient ruthenium catalyzed transfer hydrogenation of functionalized imines by isopropanol under controlled microwave heating.
2005 (English)In: Canadian journal of chemistry (Print), ISSN 0008-4042, E-ISSN 1480-3291, Vol. 83, no 6-7, 909-916 p.Article in journal (Refereed) Published
Abstract [en]

Transfer hydrogenation of various functionalized imines by isopropanol catalyzed by [Ru(CO)2(Ph4C4CO)]2 (I) was studied. The use of either an oil bath or controlled microwave heating in toluene led to an efficient procedure with high turnover frequencies and the product amines were obtained in high yields. An advantage with catalyst I over the conventional [Ru2(CO)4(Ό-H)(Ph4C4COHOCC4Ph4)] (II) is the absence of an initiation period, which results in a faster reaction with I as compared to II. [on SciFinder(R)]

Place, publisher, year, edition, pages
2005. Vol. 83, no 6-7, 909-916 p.
Keyword [en]
ruthenium catalyst transfer hydrogenation functionalized imine microwave heating
National Category
Natural Sciences
URN: urn:nbn:se:uu:diva-174520DOI: 10.1139/V05-103OAI: oai:DiVA.org:uu-174520DiVA: diva2:527599
CAPLUS AN 2005:1206597(Journal)Available from: 2012-05-21 Created: 2012-05-21 Last updated: 2012-05-21

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Samec, Joseph S. M.
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