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Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions.
2006 (English)In: Chemical Society Reviews, ISSN 0306-0012, E-ISSN 1460-4744, Vol. 35, no 3, 237-248 p.Article in journal (Refereed) Published
Abstract [en]

A review. In this tutorial review recent mechanistic studies on transition metal-catalyzed hydrogen transfer reactions are discussed. A common feature of these reactions is that they involve metal hydrides, which may be monohydrides or dihydrides. An important question is whether the substrate coordinates to the metal (inner-sphere hydrogen transfer) or if there is a direct concerted transfer of hydrogen from the metal to substrate (outer-sphere hydrogen transfer). Both exptl. and theor. studies are reviewed. [on SciFinder(R)]

Place, publisher, year, edition, pages
2006. Vol. 35, no 3, 237-248 p.
Keyword [en]
review transition metal catalyzed hydrogen transfer reaction
National Category
Natural Sciences
URN: urn:nbn:se:uu:diva-174519DOI: 10.1039/b515269kOAI: oai:DiVA.org:uu-174519DiVA: diva2:527600
CAPLUS AN 2006:183760(Journal; General Review)Available from: 2012-05-21 Created: 2012-05-21 Last updated: 2016-08-17

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Samec, Joseph S. M.Brandt, Peter.
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