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Functionalized Graphene Sheets as a Versatile Replacement for Platinum in Dye-Sensitized Solar Cells
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
2012 (English)In: ACS Applied Materials and Interfaces, ISSN 1944-8244, E-ISSN 1944-8252, Vol. 4, no 5, 2794-2800 p.Article in journal (Refereed) Published
Abstract [en]

Several techniques for fabricating functionalized graphene sheet (FGS) electrodes were tested for catalytic performance in dye-sensitized solar cells (DSSCs). By using ethyl cellulose as a sacrificial binder, and partially thermolyzing it, we were able to create electrodes which exhibited lower effective charge transfer resistance (<1 Omega cm(2)) than the thermally decomposed chloroplatinic acid electrodes traditionally used. This performance was achieved not only for the triiodide/iodide redox couple, but also for the two other major redox mediators used in DSSCs, based on cobalt and sulfur complexes, showing the versatility of the electrode. DSSCs using these FGS electrodes had efficiencies (eta) equal to or higher than those using thermally decomposed chloroplatinic acid electrodes in each of the three major redox mediators: I (eta(FGS) = 6.8%, eta(Pt) = 6.8%), Co (4.5%, 4.4%), S (3.5%, 2.0%). Through an analysis of the thermolysis of the binder and composite material, we determined that the high surface area of an electrode, as determined by nitrogen adsorption, is consistent with but not sufficient for high performing electrodes. Two other important considerations are that (i) enough residue remains in the composite to maintain structural stability and prevent restacking of FGSs upon the introduction of the solvent, and (ii) this residue must not disperse in the electrolyte.

Place, publisher, year, edition, pages
2012. Vol. 4, no 5, 2794-2800 p.
Keyword [en]
graphene, dye-sensitized solar cell, cobalt redox mediator, triiodide, sacrificial binder
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-176241DOI: 10.1021/am300451bISI: 000304285200066OAI: oai:DiVA.org:uu-176241DiVA: diva2:535194
Available from: 2012-06-19 Created: 2012-06-18 Last updated: 2017-12-07Bibliographically approved

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Boschloo, GerritHagfeldt, Anders

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