Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge
2012 (English)In: Journal of coordination chemistry (Print), ISSN 0095-8972, Vol. 65, no 15, 2713-2723 p.Article in journal (Refereed) Published
A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.
Place, publisher, year, edition, pages
2012. Vol. 65, no 15, 2713-2723 p.
Tetranuclear complexes, Iron carbonyl clusters, Hydrogenase models, X-ray crystallography, P2N2-ligands
IdentifiersURN: urn:nbn:se:uu:diva-177878DOI: 10.1080/00958972.2012.701008ISI: 000305759500011OAI: oai:DiVA.org:uu-177878DiVA: diva2:541568