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Determination of the group electronegativity of CF3 group in 3 '-O-CF3-thymidine by H-1-NMR
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
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1999 (English)In: NUCLEOSIDES & NUCLEOTIDES, ISSN 0732-8311, Vol. 18, no 4-5, 1035-1053 p.Article in journal (Other scientific) Published
Abstract [en]

The interplay of enthalpy of the gauche effect (Delta H degrees(GE)) Of the [X3'-C3'-C4'-O4'] fragment in various 3'-substituted (X) 2',3'-dideoxythymidine derivatives 1 - 7 and the inherent anomeric effect drives the two-state North reversible arrow Sout

Place, publisher, year, edition, pages
MARCEL DEKKER INC , 1999. Vol. 18, no 4-5, 1035-1053 p.
Keyword [en]
NMR COUPLING-CONSTANTS; PSEUDOROTATIONAL EQUILIBRIUM; CONFORMATIONAL-ANALYSIS; PENTOFURANOSE MOIETY; SUGAR CONFORMATION; C-NUCLEOSIDES; SUBSTITUENT ELECTRONEGATIVITIES; FURANOSE RING; PROTON; GAUCHE
Identifiers
URN: urn:nbn:se:uu:diva-27413OAI: oai:DiVA.org:uu-27413DiVA: diva2:55308
Note
Addresses: Chattopadhyaya J, Univ Uppsala, Dept Bioorgan Chem, Biomed Ctr, Box 581, S-75123 Uppsala, Sweden. Univ Uppsala, Dept Bioorgan Chem, Biomed Ctr, S-75123 Uppsala, Sweden. Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812,Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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