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Pseudorotation of the sugar moiety in pyrimidine nucleosides occurs on the same time-scale as the overall tumbling: H-2 NMR relaxation time study
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: MAGNETIC RESONANCE IN CHEMISTRY, ISSN 0749-1581, Vol. 36, no 10, 732-740 p.Article in journal (Other scientific) Published
Abstract [en]

The molecular motions of specifically deuterated thymidines 1-5a and two C-3-deuterated allofuranoses 6 and 7 were studied through temperature-dependent H-2 and C-13 relaxation times. Deuterium relaxation times in 1-5a were found in the range 20-270 ms be

Place, publisher, year, edition, pages
JOHN WILEY & SONS LTD , 1998. Vol. 36, no 10, 732-740 p.
Keyword [en]
NMR; H-2 NMR; C-13 NMR; relaxation; pseudorotation; conformation; deuterated nucleoside; NUCLEAR MAGNETIC-RESONANCE; PENTOFURANOSE MOIETY; C-NUCLEOSIDES; LARIAT-RNA; CONFORMATION; EQUILIBRIUM; DRIVE; GAUCHE; SPECTROSCOPY; ADENOSINE
Identifiers
URN: urn:nbn:se:uu:diva-27424OAI: oai:DiVA.org:uu-27424DiVA: diva2:55319
Note
Addresses: Plavec J, Natl Inst Chem, Hajdrihova 19, SI-1115 Ljubljana, Slovenia. Natl Inst Chem, SI-1115 Ljubljana, Slovenia. Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, S-75123 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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