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The electronic nature of the aglycone dictates the drive of the pseudorotational equilibrium of the pentofuranose moiety in C-nucleosides
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: NUCLEOSIDES & NUCLEOTIDES, ISSN 0732-8311, Vol. 17, no 9-11, 1605-1611 p.Article in journal (Other scientific) Published
Abstract [en]

We herein show for the first time that the specific electronic character of a C-aglycone dictates the thermodynamic preference of the two-state N reversible arrow S pseudorotational equilibrium to either N- or S-type sugar. As the electron-deficiency of t

Place, publisher, year, edition, pages
MARCEL DEKKER INC , 1998. Vol. 17, no 9-11, 1605-1611 p.
Keyword [en]
NMR COUPLING-CONSTANTS; SUBSTITUENT ELECTRONEGATIVITIES; SUGAR CONFORMATION; GAUCHE; EQUATION; THERMODYNAMICS; QUANTITATION; STRENGTH
Identifiers
URN: urn:nbn:se:uu:diva-27426OAI: oai:DiVA.org:uu-27426DiVA: diva2:55321
Note
Addresses: Chattopadhyaya J, Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, Box 581, S-75123 Uppsala, Sweden. Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, S-75123 Uppsala, Sweden. Ribozyme Pharmaceut Inc, Boulder, CO 80301 USA.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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