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The quantitation of the competing energetics of the stereoelectronic and steric effects of the 3 '-OH and the aglycone in the alpha- versus beta-D- & -L-2 '-deoxyribonucleosides by H-1-NMR
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: TETRAHEDRON, ISSN 0040-4020, Vol. 54, no 9, 1867-1900 p.Article in journal (Other scientific) Published
Abstract [en]

By comparative NMR study of 2',3'-dideoxynucleosides (see ref 1) with alpha-D- or L-2'-deoxynucleosides, we have been able to quantify for the first time the competing medium-dependent influences of the 3'-OH promoted gauche and the aglycone-configuration

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 1998. Vol. 54, no 9, 1867-1900 p.
Keyword [en]
PROTON COUPLING-CONSTANTS; HIGH-FIELD H-1-NMR; CONFORMATIONAL-ANALYSIS; PSEUDOROTATIONAL EQUILIBRIUM; PENTOFURANOSE MOIETY; SUBSTITUENT ELECTRONEGATIVITIES; BIOLOGICAL-ACTIVITY; SUGAR CONFORMATION; C-NUCLEOSIDES; FURANOSE RING
Identifiers
URN: urn:nbn:se:uu:diva-27436OAI: oai:DiVA.org:uu-27436DiVA: diva2:55331
Note
Addresses: Chattopadhyaya J, Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, Box 581, S-75123 Uppsala, Sweden. Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, S-75123 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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