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The strength of the anomeric effect in adenosine, guanosine, and in their 2'-deoxy counterparts is medium-dependent
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, Vol. 62, no 25, 8800-8808 p.Article in journal (Other scientific) Published
Abstract [en]

In nucleosides, the anomeric effect (AE) (i.e. stereoelectronic n(O4')-->sigma*(C1'-N9) interactions) places the aglycon in the pseudoaxial orientation in the N-type conformation (2'-exo-3'-endo), whereas the inherent steric effect of the nucleobase oppos

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 1997. Vol. 62, no 25, 8800-8808 p.
Keyword [en]
NMR COUPLING-CONSTANTS; PSEUDOROTATIONAL EQUILIBRIUM; PENTOFURANOSE MOIETY; CONFORMATIONAL-ANALYSIS; SUBSTITUENT ELECTRONEGATIVITIES; SUGAR CONFORMATION; C-NUCLEOSIDES; DRIVE; GAUCHE; THERMODYNAMICS
Identifiers
URN: urn:nbn:se:uu:diva-27438OAI: oai:DiVA.org:uu-27438DiVA: diva2:55333
Note
Addresses: UNIV UPPSALA, CTR BIOMED, DEPT BIOORGAN CHEM, S-75123 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-15

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