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The tunable transmission of the aromatic character of the aglycone through the anomeric effect in C-nucleosides drives its own sugar conformation: A thermodynamic study
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: TETRAHEDRON, ISSN 0040-4020, Vol. 53, no 18, 6433-6464 p.Article in journal (Other scientific) Published
Abstract [en]

The anomeric and the gauche effects are two competing stereoelectronic forces that drive the North (N) (C2'-exo-C3'-endo) reversible arrow South (S) (C2'-endo-C3'-exo) pseudorotational equilibrium in nucleosides (ref 1). The quantitation of the energetics

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 1997. Vol. 53, no 18, 6433-6464 p.
Keyword [en]
NMR COUPLING-CONSTANTS; PSEUDOROTATIONAL EQUILIBRIUM; PENTOFURANOSE MOIETY; SUBSTITUENT ELECTRONEGATIVITIES; FURANOSE RING; ORIGIN; GAUCHE; NUCLEOTIDES; CHEMISTRY; ETHANES
Identifiers
URN: urn:nbn:se:uu:diva-27448OAI: oai:DiVA.org:uu-27448DiVA: diva2:55343
Note
Addresses: UNIV UPPSALA, CTR BIOMED, DEPT BIOORGAN CHEM, S-75123 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-15

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