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The Chemical Bond in Carbonyl and Sulfinyl Groups Studied by Soft X-ray Spectroscopy and ab Initio Calculations
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2012 (English)In: ChemPhysChem, ISSN 1439-4235, E-ISSN 1439-7641, Vol. 13, no 13, 3106-3111 p.Article in journal (Refereed) Published
Abstract [en]

The polar character of the sulfinyl bond, which determines many of the properties of dimethyl sulfoxide (DMSO), is a result of charge transfer in low-lying π-type orbitals. This characteristic—together with the wide energy gap between the highest occupied and the lowest unoccupied molecular orbitals of this substance—makes DMSO a relatively inert aprotic solvent with strong nucleophilicity and electrophilicity.

Place, publisher, year, edition, pages
2012. Vol. 13, no 13, 3106-3111 p.
Keyword [en]
ab initio calculations, acetone, chemical bond, dimethyl sulfoxide, X-ray spectroscopy
National Category
Natural Sciences
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URN: urn:nbn:se:uu:diva-185210DOI: 10.1002/cphc.201200314ISI: 000308465700007OAI: oai:DiVA.org:uu-185210DiVA: diva2:571324
Available from: 2012-11-22 Created: 2012-11-21 Last updated: 2017-12-07Bibliographically approved

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Rubensson, Jan-Erik

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