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Molybdenum Hexacarbonyl Mediated CO Gas-Free Carbonylative Reactions
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Organic Pharmaceutical Chemistry.
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Organic Pharmaceutical Chemistry.
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Organic Pharmaceutical Chemistry.
2012 (English)In: Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, ISSN 0936-5214, E-ISSN 1437-2096, no 5, 685-698 p.Article in journal (Refereed) Published
Abstract [en]

This Account summarizes predominately our own experiences in developing microwave-heated palladium-catalyzed Mo(CO)6-mediated gas-free carbonylative reactions, although contributions from other groups, including non-palladium-catalyzed examples, have also been covered. Presented reactions include amino-, amido-, and alkoxycarbonylations as well as carbonylative cyclizations and carbonylative cross-couplings, using Mo(CO)6 as a solid source of CO. The methodology was developed mainly for rapid small-scale applications, avoiding the problematic use of gaseous CO in a standard laboratory. In most cases, the reported Mo(CO)6-mediated carbonylations were conducted in sealed vessels and with reaction times of less than 1 hour. The Account also highlights relevant applications in medicinal and high-speed chemistry.

Place, publisher, year, edition, pages
2012. no 5, 685-698 p.
Keyword [en]
carbonylation, molybdenum, multicomponent reaction, palladium, catalysis
National Category
Medical and Health Sciences Medicinal Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-187859DOI: 10.1055/s-0031-1290350ISI: 000301343400003OAI: oai:DiVA.org:uu-187859DiVA: diva2:575742
Note

Dedicated to Prof. Anders Hallberg on the occasion of his 67th birthday

Available from: 2012-12-11 Created: 2012-12-11 Last updated: 2017-12-07Bibliographically approved

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Odell, Luke R.Larhed, Mats

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