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Li intercalation in transparent Ti-Ce oxide films: Energetics and ion dynamics
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.ORCID iD: 0000-0002-5496-9664
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.ORCID iD: 0000-0002-8279-5163
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.
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1997 (English)In: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 81, no 9, 6432-6437 p.Article in journal (Refereed) Published
Abstract [en]

Films of Ti dioxide, mixed Ti–Ce oxide, and Ce dioxide were produced by reactive dc magnetron sputtering.Electrochemical lithiation was probed by chronopotentiometry, cyclic voltammetry together with optical transmittance recording, and impedance spectroscopy. Evidence was found for inserted electrons being accommodated in Ce4f states; this contention was supported by preliminary results from x-rayabsorption fine-structure spectroscopy. These electrons do not produce luminous electrochromism. The variation of the chemical diffusion coefficient of Li, with film composition and Li content, was also studied.

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1997. Vol. 81, no 9, 6432-6437 p.
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Engineering and Technology
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URN: urn:nbn:se:uu:diva-30207DOI: 10.1063/1.364424OAI: oai:DiVA.org:uu-30207DiVA: diva2:58103
Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2017-12-06Bibliographically approved

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Strömme, MariaNiklasson, Gunnar A.Granqvist, Claes-Göran

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