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Zr-Ce Oxides as Candidates for Optically Passive Counter Electrodes
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.ORCID iD: 0000-0002-5496-9664
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science.
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1999 (English)In: Solar Energy Materials and Solar Cells, ISSN 0927-0248, E-ISSN 1879-3398, Vol. 56, no 3-4, 223-230 p.Article in journal (Refereed) Published
Abstract [en]

Zr-Ce oxide films with compositions from pure Zr oxide to pure Ce oxide were made by reactive DC magnetron co-sputtering. The composition and structure were determined by Rutherford backscattering and X-ray diffraction. Pure Ce oxide films have high charge capacity and are optically passive under charge insertion; they are, however, chemically unstable in an electrolyte of LiClO4 in propylene carbonate. Pure Zr oxide has practically zero charge capacity. Zr-Ce oxide films have high (above 80%) optical transmittance, high charge capacity, and good chemical stability. These films remain fully transparent irrespective of their degree of lithiation, which may be reconciled with electrons accommodating 4f states of Ce.

Place, publisher, year, edition, pages
1999. Vol. 56, no 3-4, 223-230 p.
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Engineering and Technology
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URN: urn:nbn:se:uu:diva-30418DOI: 10.1016/S0927-0248(98)00132-9Scopus ID: 2-s2.0-0032712459OAI: oai:DiVA.org:uu-30418DiVA: diva2:58314
Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2017-12-06Bibliographically approved

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Strömme, MariaKullman, LisenGranqvist, Claes-Göran

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