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Angular and dynamical properties in resonant inelastic x-ray scattering: Case study of chlorine-containing molecules
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2012 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 86, no 1, 013407Article in journal (Refereed) Published
Abstract [en]

Polarization-dependent resonant inelastic x-ray scattering (RIXS) has been shown to be a probe of molecular-field effects on the electronic structure of isolated molecules. In this experimental analysis we explain the linear dichroism observed in Cl 2p polarized RIXS following Cl 1s excitation of a series of chlorofluoromethanes (CF3Cl, CF2Cl2, CFCl3, and CCl4) as due to molecular-field effects, including singlet-triplet exchange. We present an approach to extract directly the 2p inner-shell electronic state populations from the experimental measurements. Using the angular properties of the measured KV emission we also are able to determine the value of the polarization anisotropy parameter beta(p) for each resolved component of the KV emission spectra.

Place, publisher, year, edition, pages
2012. Vol. 86, no 1, 013407
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Physical Sciences
URN: urn:nbn:se:uu:diva-191249DOI: 10.1103/PhysRevA.86.013407ISI: 000306307200006OAI: oai:DiVA.org:uu-191249DiVA: diva2:585147

Correction in: Physical Review A, 2012, vol. 86, issue 3, article no. 039903, doi: 10.1103/PhysRevA.86.039903

Available from: 2013-01-09 Created: 2013-01-09 Last updated: 2015-05-26Bibliographically approved

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Piancastelli, Maria Novella
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Surface and Interface Science
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