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Mn2FeSbO6: A ferrimagnetic ilmenite and an antiferromagnetic perovskite
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
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2013 (English)In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 87, no 1, 014408- p.Article in journal (Refereed) Published
Abstract [en]

Due to its polymorphism, Mn2FeSbO6 can be synthesized at high pressures and temperatures as a ferrimagnetic ilmenite or an antiferromagnetic perovskite. The structural phase transformation is discussed in detail, and magnetic structures are proposed for both phases. The high-pressure Mn2FeSbO6 polymorph is a rare example of A(2)B'B '' O-6 perovskite with solely Mn cations on the A site. Fe and Sb cations are ordered on the B sites. Theoretical calculations for the perovskite phase suggest a complex magnetic structure, holding an electronic polarization.

Place, publisher, year, edition, pages
2013. Vol. 87, no 1, 014408- p.
National Category
Natural Sciences Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
URN: urn:nbn:se:uu:diva-193485DOI: 10.1103/PhysRevB.87.014408ISI: 000313157100002OAI: oai:DiVA.org:uu-193485DiVA: diva2:603235
Available from: 2013-02-05 Created: 2013-02-04 Last updated: 2017-12-06Bibliographically approved

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Mathieu, RolandIvanov, Sergey A.Puri, Anil KumarLazor, PeterNordblad, Per

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