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Toward Metathesis Reactions on Vinylphosphaalkenes
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
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2013 (English)In: Phosphorus Sulfur and Silicon and the Related Elements, ISSN 1042-6507, E-ISSN 1563-5325, Vol. 188, no 1-3, 152-158 p.Article in journal (Refereed) Published
Abstract [en]

Attempts to utilize C-ethylenic phosphaalkenes in metathesis reactions are discussed. Unprecedented reactivity is observed where the vinylphosphaalkene undergoes the first step of the catalytic cycle and cross-metathesis with the phenylmethylene moiety of Grubbs 2nd generation catalyst. However, homo-metathesis reaction to form 1,6-diphosphahexa-1,3,5-triene is not observed, presumably due to steric constraints.

Place, publisher, year, edition, pages
2013. Vol. 188, no 1-3, 152-158 p.
Keyword [en]
Phosphaalkene, olefin, -conjugation, metathesis
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-203694DOI: 10.1080/10426507.2012.743145ISI: 000319042300042OAI: oai:DiVA.org:uu-203694DiVA: diva2:637355
Available from: 2013-07-17 Created: 2013-07-17 Last updated: 2017-12-06Bibliographically approved

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Öberg, ElisabetOrthaber, AndreasOtt, Sascha

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