Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach
2013 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 49, no 57, 6412-6414 p.Article in journal (Refereed) Published
A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)<^>N(py)<^>C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe-II bis-terpyridine complex.
Place, publisher, year, edition, pages
2013. Vol. 49, no 57, 6412-6414 p.
IdentifiersURN: urn:nbn:se:uu:diva-204297DOI: 10.1039/c3cc43833cISI: 000320709000016OAI: oai:DiVA.org:uu-204297DiVA: diva2:638225