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Towards longer-lived metal-to-ligand charge transfer states of iron(II) complexes: an N-heterocyclic carbene approach
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2013 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 49, no 57, 6412-6414 p.Article in journal (Refereed) Published
Abstract [en]

A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)<^>N(py)<^>C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe-II bis-terpyridine complex.

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2013. Vol. 49, no 57, 6412-6414 p.
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Natural Sciences
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URN: urn:nbn:se:uu:diva-204297DOI: 10.1039/c3cc43833cISI: 000320709000016OAI: oai:DiVA.org:uu-204297DiVA: diva2:638225
Available from: 2013-07-29 Created: 2013-07-29 Last updated: 2017-12-06

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Göransson, ErikLomoth, Reiner

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