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Laboratory-frame electron angular distributions: Probing the chemical environment through intramolecular electron scattering
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
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2013 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 87, no 6, 063420- p.Article in journal (Refereed) Published
Abstract [en]

Carbon 1s photoelectron asymmetry parameters beta for the chlorinated and the methyl carbon atom of CH3CH2Cl, CH3CHCl2, and CH3CCl3 have been measured using synchrotron radiation in the 340-600 eV energy range. We provide experimental evidence that the intramolecular scattering strongly affects beta values, even far from the ionization threshold. The results are in agreement with B-spline density functional theory calculations, making it possible to single out the behavior of the various continuum partial waves. We conclude that the intramolecular scattering makes electron angular distributions sensitive to the chemical environment, even in isolated gas phase molecules.

Place, publisher, year, edition, pages
2013. Vol. 87, no 6, 063420- p.
National Category
Physical Sciences
Research subject
Physics with spec. in Atomic, Molecular and Condensed Matter Physics
URN: urn:nbn:se:uu:diva-204801DOI: 10.1103/PhysRevA.87.063420ISI: 000320764300013OAI: oai:DiVA.org:uu-204801DiVA: diva2:641064
Swedish Research CouncilEU, European Research Council
Available from: 2013-08-15 Created: 2013-08-12 Last updated: 2015-12-04Bibliographically approved

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Söderström, JohanSvensson, SvanteMårtensson, Nils
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