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Structure of a transient neutral histidine radical in solution: EPR continuous-flow studies in a Ti3+/EDTA-Fenton system and density functional calculations
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Physics, Department of Quantum Chemistry.
2000 (English)In: JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, Vol. 104, no 40, 9144-9152 p.Article in journal (Refereed) Published
Abstract [en]

Oxidation of histidine by OH* radicals has been studied at room temperature over a large range of pH values in a Ti3+/EDTA/H2O2-Fenton system using a special EPR continuous-flow setup. At pH 7 to 8, during fast flow, an EPR spectrum from a new transient h

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2000. Vol. 104, no 40, 9144-9152 p.
Keyword [en]
ELECTRON-SPIN RESONANCE; GAUSSIAN-BASIS SETS; RIBONUCLEOTIDE REDUCTASE; ENDOR SPECTROSCOPY; IMIDAZOLE; MODEL; WATER
Identifiers
URN: urn:nbn:se:uu:diva-36858OAI: oai:DiVA.org:uu-36858DiVA: diva2:64757
Note
Addresses: Lassmann G, Tech Univ Berlin, Max Volmer Inst Biophys & Biochem, D-10623 Berlin, Germany. Tech Univ Berlin, Max Volmer Inst Biophys & Biochem, D-10623 Berlin, Germany. Uppsala Univ, Dept Quantum Chem, S-75120 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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