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Alternative pathways for the C2-C3 bond cleavage and C2 configuration inversion processes for the Rubisco-catalyzed carboxylation sequence
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry.
2000 (English)In: CHEMICAL PHYSICS LETTERS, ISSN 0009-2614, Vol. 318, no 4-5, 361-369 p.Article in journal (Refereed) Published
Abstract [en]

Alternative reaction mechanisms for C2-C3 bond-breaking and inversion of configuration at C2 within the carboxylation path of Rubisco substrate, D-ribulose 1,5-bisphosphate, are investigated. Hartree-Fock calculations were carried out at 3-21G and 6-31G**

Place, publisher, year, edition, pages
ELSEVIER SCIENCE BV , 2000. Vol. 318, no 4-5, 361-369 p.
Keyword [en]
TRANSITION STRUCTURES; RIBULOSE-1;5-BISPHOSPHATE CARBOXYLASE; RIBULOSE 1;5-BISPHOSPHATE; ENZYME CATALYSIS; ACTIVE-SITE; OXYGENASE; SUBSTRATE; MECHANISM; BISPHOSPHATE; ENOLIZATION
Identifiers
URN: urn:nbn:se:uu:diva-37073OAI: oai:DiVA.org:uu-37073DiVA: diva2:64972
Note
Addresses: Andres J, Univ Jaume I, Dept Ciencies Expt, Box 224, E-12080 Castello, Spain. Univ Jaume I, Dept Ciencies Expt, E-12080 Castello, Spain. Univ Uppsala, Dept Phys Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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