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Proton-coupled electron transfer from tyrosine in a tyrosine-ruthenium-tris-bipyridine complex: Comparison with Tyrosine(z) oxidation in photosystem II
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry.
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2000 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, Vol. 122, no 16, 3932-3936 Language: English p.Article in journal (Refereed) Published
Abstract [en]

The pH- and the temperature dependence of the rate constant for electron transfer from tyrosine to ruthenium in Ru(II)(bpy)(2)(4-Me-4'CONH-L-tyrosine etyl ester-2,2'-bpy) 2PF(6) was investigated using flash photolysis. At a pH below the tyrosine pK(a) app

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2000. Vol. 122, no 16, 3932-3936 Language: English p.
Keyword [en]
WATER OXIDATION; INVOLVEMENT; CHEMISTRY; DYNAMICS
Identifiers
URN: urn:nbn:se:uu:diva-37082OAI: oai:DiVA.org:uu-37082DiVA: diva2:64981
Note
Addresses: Hammarstrom L, Univ Uppsala, Dept Phys Chem, Box 532, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Phys Chem, S-75121 Uppsala, Sweden. Univ Lund, Dept Biochem, Ctr Chem & Chem Engn, S-22100 Lund, Sweden. Univ Stockholm, Arrhenius Lab, Dept OrganAvailable from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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