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Vibrational mode-specific photochemical reaction dynamics of chlorine dioxide in solution
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry.
2001 (English)In: JOURNAL OF CHEMICAL PHYSICS, ISSN 0021-9606, Vol. 114, no 15, 6781-6794 p.Article in journal (Refereed) Published
Abstract [en]

We study the reaction dynamics of OClO in cyclohexane, acetonitrile, and water by femtosecond pump-probe spectroscopy. In all solvents we observe a quantum beat in a 403 nm one-color pump-probe experiment with 55 fs temporal resolution, that decays with a

Place, publisher, year, edition, pages
AMER INST PHYSICS , 2001. Vol. 114, no 15, 6781-6794 p.
Keyword [en]
PHOTOINDUCED MOLECULAR DETACHMENT; RESONANCE RAMAN INTENSITIES; POTENTIAL-ENERGY SURFACES; FEMTOSECOND PUMP-PROBE; PHOTODISSOCIATION DYNAMICS; AQUEOUS-SOLUTION; CONDENSED-PHASE; ULTRAFAST PHOTODISSOCIATION; OCLO PHOTODISSOCIATION; GEMINATE RECOMBINATION
Identifiers
URN: urn:nbn:se:uu:diva-37177OAI: oai:DiVA.org:uu-37177DiVA: diva2:65076
Note
Addresses: Fidder H, Univ Uppsala, Dept Phys Chem, Box 532, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Phys Chem, S-75121 Uppsala, Sweden. Max Born Inst Nichtlineare Opt & Kurzzeitspekt, D-12489 Berlin, Germany.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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