Voltammetric and spectroscopic characterization of early intermediates in the Co(II)-polypyridyl-catalyzed reduction of water
2013 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 49, no 77, 8638-8640 p.Article in journal (Refereed) Published
Early intermediates of catalytic water reduction by a Co(II)-polypyridyl species have been characterized. Electrochemical detection of the Co(III)-hydride and time-resolved spectroscopic detection of the Co(I)-ligand intermediates provide an understanding of their reactivity in electrolytic or light-driven reduction of protons to hydrogen.
Place, publisher, year, edition, pages
2013. Vol. 49, no 77, 8638-8640 p.
IdentifiersURN: urn:nbn:se:uu:diva-208179DOI: 10.1039/c3cc44655gISI: 000323758900017OAI: oai:DiVA.org:uu-208179DiVA: diva2:651170