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Highly diastereoselective reaction of 2-azanorbornyl enolates with electrophiles
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
1999 (English)In: ORGANIC LETTERS, ISSN 1523-7060, Vol. 1, no 10, 1595-1597 p.Article in journal (Refereed) Published
Abstract [en]

A highly diastereoselective reaction of 2-azanorbornyl enolates with electrophiles has been studied. Deprotonation of 4 with LDA at low temperature affords the corresponding exocyclic lithium enolate 5, which reacts with different electrophiles such as al

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 1999. Vol. 1, no 10, 1595-1597 p.
Keyword [en]
DIELS-ALDER REACTION; ENANTIOSELECTIVE ADDITION; DIALKYLZINC REAGENTS; ALDEHYDES; DERIVATIVES; CATALYSTS; ALKYLATIONS; GLYOXYLATE; REDUCTION; KETONES
Identifiers
URN: urn:nbn:se:uu:diva-37565OAI: oai:DiVA.org:uu-37565DiVA: diva2:65464
Note
Addresses: Andersson PG, Univ Uppsala, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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