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2-azanorbornyl alcohols: Very efficient ligands for ruthenium-catalyzed asymmetric transfer hydrogenation of aromatic ketones
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
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2000 (English)In: JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, Vol. 65, no 10, 3116-3122 p.Article in journal (Refereed) Published
Abstract [en]

2-Azanorbornyl-derived amino alcohols were prepared and evaluated as ligands in the Ru(II)-catalyzed asymmetric transfer hydrogenation of aromatic ketones. To improve selectivity and rate, the structure of the ligand was optimized, Acetophenone was reduce

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2000. Vol. 65, no 10, 3116-3122 p.
Keyword [en]
ENANTIOSELECTIVE TRANSFER HYDROGENATION; HIGHLY EFFICIENT; CHIRAL LIGANDS; ALPHA;BETA-UNSATURATED KETONES; TRANSFER REDUCTION; CARBONYL-COMPOUNDS; ALLYLIC ALCOHOLS; SCHIFF-BASES; COMPLEXES; OXAZABOROLIDINES
Identifiers
URN: urn:nbn:se:uu:diva-37566OAI: oai:DiVA.org:uu-37566DiVA: diva2:65465
Note
Addresses: Andersson PG, Univ Uppsala, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden. Solvias AG, Catalysis Res, CH-4002 Basel, Switzerland.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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