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A radical cyclization route to pyrrolidines based on conjugate addition to electron deficient phenylselenenylalkenes
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: TETRAHEDRON LETTERS, ISSN 0040-4039, Vol. 41, no 19, 3701-3704 p.Article in journal (Refereed) Published
Abstract [en]

alpha-Phenylselenenyl-alpha,beta-unsaturated esters, amides, ketones, nitriles and sulfones were prepared by zinc chloride promoted chloroselenation/dehydrochlorination of the corresponding alpha,beta-unsaturated compounds. After Michael addition of allyl

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2000. Vol. 41, no 19, 3701-3704 p.
Keyword [en]
selenium and compounds; radicals and radical reactions; pyrrolidines; addition reactions; STEREOSELECTIVE SYNTHESIS; VINYLIC SELENIDES; SUBSTITUENT; OLEFINS; 1-SELENO-2-SILYLETHENES; DERIVATIVES; CHLORIDE; BEARING
Identifiers
URN: urn:nbn:se:uu:diva-37570OAI: oai:DiVA.org:uu-37570DiVA: diva2:65469
Note
Addresses: Engman L, Univ Uppsala, Inst Chem, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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