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A rigid dirhodium(II) carboxylate as an efficient catalyst for the asymmetric cyclopropanation of olefins
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, Vol. 603, no 1, 13-17 p.Article in journal (Refereed) Published
Abstract [en]

The dirhodium(II) complex 7 of (1S,3R,4R)-2-(p-tert-butylphenylsulphonyl)-2-aza-bicycol[2.2.1]heptane-3-carboxylic acid (3) (or its enantiomer) was synthesised in four steps from cyclopentadiene, (R)- or (S)-phenylethylamine and methyl glyoxylate. Complex

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA , 2000. Vol. 603, no 1, 13-17 p.
Keyword [en]
rhodium; cyclopropanation; asymmetric catalysis; METAL CARBENE TRANSFORMATIONS; BRIDGING PROLINATE LIGANDS; DIELS-ALDER REACTION; ENANTIOSELECTIVE CATALYSTS; CHIRAL LIGANDS; RHODIUM(II)-STABILIZED VINYLCARBENOIDS; METHYL PHENYLDIAZOACETATE; TRANSFER HYDRO
Identifiers
URN: urn:nbn:se:uu:diva-37571OAI: oai:DiVA.org:uu-37571DiVA: diva2:65470
Note
Addresses: Andersson PG, Univ Uppsala, Dept Organ Chem, Inst Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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