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Evidence for the intermediacy of (eta(3)-allyl)palladium complexes in the palladium-catalyzed acryloxylation of cycloalkenes: Unexpected oxidation of 1,5-cyclooctadiene
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
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2000 (English)In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, no 1, 219-224 p.Article in journal (Refereed) Published
Abstract [en]

Palladium-catalyzed acryloxylation of several cycloalkenes in the presence of the Pd(OAc)(2)/p-benzoquinone/MnO2 catalytic system is reported. This oxidation reaction yields allylic acrylates as the sole products through the intermediacy of an eta(3)-ally

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2000. no 1, 219-224 p.
Keyword [en]
homogeneous catalysis; palladium; acetoxylation; acryloxylation; 1;2-addition reactions; 1;5-cyclooctadiene; cyclooct-4-enone; METHYLENE-GAMMA-BUTYROLACTONES; ALLYLIC ACETOXYLATION; ALKENES
URN: urn:nbn:se:uu:diva-37578OAI: oai:DiVA.org:uu-37578DiVA: diva2:65477
Addresses: Waegell B, Fac Sci St Jerome, CNRS, Lab Stereochim, Ave Escadrille Normandie Niemen Case 532, F-13397 Marseille 20, France. Fac Sci St Jerome, CNRS, Lab Stereochim, F-13397 Marseille 20, France. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, SAvailable from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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