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An enantioselective route to paeonilactone A via palladium- and copper-catalyzed reactions
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, Vol. 65, no 7, 2122-2126 p.Article in journal (Refereed) Published
Abstract [en]

We herein report on a formal total synthesis of paeonilactone A involving palladium-, copper-, and enzyme-catalyzed reactions starting from 1,3-cyclohexadiene. The key step in the synthesis, a palladium(II)-catalyzed 1,4-oxylactonization of a conjugated d

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2000. Vol. 65, no 7, 2122-2126 p.
Keyword [en]
STEREOCONTROLLED LACTONIZATION REACTIONS; STEREOSELECTIVE SYNTHESIS; ORGANOPALLADIUM ROUTE; NATURAL-PRODUCTS; EPOXY ALCOHOLS; R-(-)-CARVONE; HALOHYDRINS; EPOXIDATION
Identifiers
URN: urn:nbn:se:uu:diva-37580OAI: oai:DiVA.org:uu-37580DiVA: diva2:65479
Note
Addresses: Ronn M, Roche Colorado Corp, 2075 N 55th St, Boulder, CO 80301 USA. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Univ Uppsala, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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