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Stereoselective route towards 2,5-disubstituted piperidine alkaloids. Synthesis of (+)-pseudoconhydrine and (+/-)-epi-pseudoconhydrine
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: TETRAHEDRON, ISSN 0040-4020, Vol. 56, no 15, 2225-2230 p.Article in journal (Refereed) Published
Abstract [en]

This paper describes a new general approach towards functionalized piperidine alkaloids, based on the stereo- and regioselective palladium(0)-catalyzed nucleophilic ring-opening of vinyl epoxides by nitrogen nucleophiles. The latter reaction provides acce

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2000. Vol. 56, no 15, 2225-2230 p.
Keyword [en]
(+)-pseudoconhydrine; (+/-)-epi-pseudoconhydrine; STEREOCONTROLLED ORGANOPALLADIUM ROUTE; ASYMMETRIC-SYNTHESIS; DERIVATIVES; RESOLUTION; VENOM; ACID
Identifiers
URN: urn:nbn:se:uu:diva-37587OAI: oai:DiVA.org:uu-37587DiVA: diva2:65486
Note
Addresses: Backvall JE, Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Uppsala Univ, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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