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A general approach to indolizidine alkaloids from 1-benzyloxy-5-(p-toluenesulfonamido)-3-alken-2-ols: Synthesis of (+)-monomorine I
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
1999 (English)In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, no 12, 3277-3280 p.Article in journal (Refereed) Published
Abstract [en]

A versatile method for the preparation of indolizidine alkaloids from 1-benzyloxy-5-(p-toluenesulfonamido)-3-alken-2-ols as stereodefined key intermediates has been developed. The utility of this approach was demonstrated by the synthesis of (+)-monomorin

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 1999. no 12, 3277-3280 p.
Keyword [en]
alkaloids; asymmetric synthesis; palladium; amino alcohols; natural products; monomorine I; ENANTIOSELECTIVE TOTAL SYNTHESIS; ASYMMETRIC-SYNTHESIS; ROUTE; (+/-)-MONOMORINE-I; DERIVATIVES; ALKYLATION; OXIDANTS; 195B
Identifiers
URN: urn:nbn:se:uu:diva-37600OAI: oai:DiVA.org:uu-37600DiVA: diva2:65499
Note
Addresses: Backvall JE, Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Univ Uppsala, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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