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Synthesis of oxonium derivatives of the dodecahydro-closo-dodecaborate anion [B12H12](2-). Tetramethylene oxonium derivative of [B12H12](2-) as a convenient precursor for the synthesis of functional compounds for boron neutron capture therapy
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
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2000 (English)In: POLYHEDRON, ISSN 0277-5387, Vol. 19, no 6, 627-632 p.Article in journal (Refereed) Published
Abstract [en]

Direct synthesis of oxonium derivatives of the dodecahydro-closo-dodecaborate anion is described and the reaction mechanism is discussed. Various derivatives of the [B12H12](2-) anion containing hydroxyl, amine, acid, and amino acid functions were prepare

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2000. Vol. 19, no 6, 627-632 p.
Keyword [en]
closo-dodecaborate; oxonium derivatives; functional derivatives; amino acids; boron neutron capture therapy; ORGANOSULFUR CHEMISTRY; ACYL DERIVATIVES; NMR-SPECTRA; 1;3-DITHIANES; COMPLEXES; BRIDGES; LIGANDS; COBALT; ALKYL
Identifiers
URN: urn:nbn:se:uu:diva-37603OAI: oai:DiVA.org:uu-37603DiVA: diva2:65502
Note
Addresses: Sivaev IB, Russian Acad Sci, Inst Organoelement Cpds, Vavilov St 28, Moscow 117813, Russia. Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia. Univ Uppsala, Dept Inorgan Chem, Inst Chem, S-75121 Uppsala, Sweden. Univ Munich, InstAvailable from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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