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Novel preparation of alpha,beta-unsaturated aldehydes. Benzeneselenolate promotes elimination of HBr from alpha-bromoacetals
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, Vol. 65, no 7, 2151-2162 p.Article in journal (Refereed) Published
Abstract [en]

Acetalization, alpha-bromination, nucleophilic phenylselenenylation, oxidative elimination/hydrolysis was investigated as a novel protocol for the alpha,beta-dehydrogenation of aldehydes. Treatment of acetals with bromine in methylene chloride afforded th

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2000. Vol. 65, no 7, 2151-2162 p.
Keyword [en]
CARBONYL-COMPOUNDS; ORGANOSELENIUM CHEMISTRY; ASYMMETRIC-SYNTHESIS; ORGANIC-SYNTHESIS; KETONES; REAGENTS; ETHERS; ACIDS; STEREOCHEMISTRY; DERIVATIVES
Identifiers
URN: urn:nbn:se:uu:diva-37610OAI: oai:DiVA.org:uu-37610DiVA: diva2:65509
Note
Addresses: Engman L, Univ Uppsala, Inst Chem, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, Dept Organ Chem, S-75121 Uppsala, Sweden. ND Zelinskii Organ Chem Inst, Moscow 117913, Russia.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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