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Synthesis of 3(Z)-dodecen-12-olide - an aggregation pheromone of the flat grain beetle Cryptolestes pusillus (Coleoptera : Cucujidae)
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: RUSSIAN CHEMICAL BULLETIN, ISSN 1066-5285, Vol. 49, no 7, 1297-1300 p.Article in journal (Refereed) Published
Abstract [en]

3(Z)-Dodecen-12-olide, an aggregation pheromone of the flat grain beetle, was obtained using 1,4-cis-hydrogenation of ethyl 12-hydroxydodeca-2,4-dienoate as a key step. The dienoic ester was synthesized from 10-hydroxydec-2-enal, which, in turn, was prepa

Place, publisher, year, edition, pages
CONSULTANTS BUREAU , 2000. Vol. 49, no 7, 1297-1300 p.
Keyword [en]
acetals; bromination; selenation; 3(Z)-dodecen-12-olide; 10-hydroxydec-2-enal; aldehydes; organoselenium compounds; 1;4-cis-hydrogenation; STEREOCONTROLLED SYNTHESIS; CONVENIENT PROTOCOL; ORYZAEPHILUS; BROMINATION; EFFICIENT; ALDEHYDES; OXIDATION; ALCOHOL
Identifiers
URN: urn:nbn:se:uu:diva-37611OAI: oai:DiVA.org:uu-37611DiVA: diva2:65510
Note
Addresses: Vasil'ev AA, Russian Acad Sci, ND Zelinskii Organ Chem Inst, 47 Leninsky Prosp, Moscow 117813, Russia. Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117813, Russia. Univ Uppsala, Dept Organ Chem, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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