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Alkene-alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2000 (English)In: MENDELEEV COMMUNICATIONS, ISSN 0959-9436, no 3, 101-102 p.Article in journal (Refereed) Published
Abstract [en]

Stereospecific synthesis of erythro-5-benzyloxy-2,3-dimethylpentan-1-ol, a building block for the preparation of faranal and lasiol, was performed starting from 5-benzyloxypent-2-yn-1-ol using the title methodology followed by 1,2-syn-hydrogenation.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2000. no 3, 101-102 p.
Keyword [en]
MANDIBULAR GLAND SECRETION; CATALYZED ENYNE METATHESIS; TRAIL PHEROMONE; LASIUS-MERIDIONALIS; STEREOCONTROLLED SYNTHESIS; CONVENIENT PROTOCOL; 1;3-DIENE SYNTHESIS; PHARAOHS ANT; ENANTIOMERS; OXIDATION
Identifiers
URN: urn:nbn:se:uu:diva-37613OAI: oai:DiVA.org:uu-37613DiVA: diva2:65512
Note
Addresses: Vasil'ev AA, Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 117913, Russia. Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 117913, Russia. Univ Uppsala, Inst Chem, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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