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The RNA molecular wire: the pH-dependent change of the electronic character of adenin-9-yl is transmitted to drive the sugar and phosphate torsions in adenosine 3 ',5 '-bisphosphate
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Faculty of Science and Technology, Biology, Department of Bioorganic Chemistry.
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2000 (English)In: JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, ISSN 0894-3230, Vol. 13, no 5, 300-305 p.Article in journal (Refereed) Published
Abstract [en]

The change of the electronic character of adenin-9-yl in adenosine 3',5'-bisphosphate (EtpApMe, 1) in the neutral versus protonated form, in contrast to its abasic counterpart [Etp(apurinic)pMe, 2], is transmitted to modulate the sugar conformation by an

Place, publisher, year, edition, pages
JOHN WILEY & SONS LTD , 2000. Vol. 13, no 5, 300-305 p.
Keyword [en]
NMR conformation; adenosine 3 ';5 '-bisphosphate; protonation; RNA; anomeric and gauche effects; NMR COUPLING-CONSTANTS; PSEUDOROTATIONAL EQUILIBRIUM; CONFORMATIONAL-ANALYSIS; PENTOFURANOSE MOIETY; SUBSTITUENT ELECTRONEGATIVITIES; KARPLUS EQUATION; C-NUCL
Identifiers
URN: urn:nbn:se:uu:diva-37614OAI: oai:DiVA.org:uu-37614DiVA: diva2:65513
Note
Addresses: Chattopadhyaya J, Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, Box 581, S-75123 Uppsala, Sweden. Univ Uppsala, Ctr Biomed, Dept Bioorgan Chem, S-75123 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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