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Intramolecular amidomercurations under allylic control: a stereoselective synthesis of (+)-pseudohygroline and (+)-3-hydroxypyrrolizidine
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
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2001 (English)In: TETRAHEDRON-ASYMMETRY, ISSN 0957-4166, Vol. 12, no 4, 597-604 p.Article in journal (Refereed) Published
Abstract [en]

The diastereoselectivity of intramolecular amidomercurations can be reversed by altering the remote allylic substituent of omega -alkenylcarbamates. This methodology has been applied to the synthesis of (+)-pseudohygroline and (+)-3-hydroxypyrrolizidine.

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2001. Vol. 12, no 4, 597-604 p.
Keyword [en]
OXYMERCURATIONS; ALKALOIDS
Identifiers
URN: urn:nbn:se:uu:diva-37628OAI: oai:DiVA.org:uu-37628DiVA: diva2:65527
Note
Addresses: Perlmutter P, Monash Univ, Dept Chem, POB 23, Clayton, Vic 3800, Australia. Monash Univ, Dept Chem, Clayton, Vic 3800, Australia. Uppsala Univ, Dept Organ Chem, Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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