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Determination of absolute configuration of (pi-allyl)palladium complexes by NMR spectroscopy and stereoselective complexation
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry.
2001 (English)In: Chemistry-A European Journal, ISSN 0947-6539, Vol. 7, no 2, 396-403 p.Article in journal (Refereed) Published
Abstract [en]

The chiral chelating ligand N,N'-bis(phenylethyl)bispidine (1) forms a rigid cavity which accommodates (rc-allyl)palladium species with high selectivity In the resulting complex, the absolute configuration of the re-allyl ligand can be determined by the d

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2001. Vol. 7, no 2, 396-403 p.
Keyword [en]
absolute configuration; allyl ligands; chelates; chiral resolution; NMR spectroscopy; palladium; ASYMMETRIC ALLYLIC ALKYLATION; X-RAY STRUCTURE; PI-ALLYL; PALLADIUM COMPLEXES; CHIRAL LIGANDS; ASSIGNMENT; ESTABLISHMENT; DERIVATIVES; RESONANCE; CATALYSIS
Identifiers
URN: urn:nbn:se:uu:diva-37637DOI: 10.1002/1521-3765(20010119)OAI: oai:DiVA.org:uu-37637DiVA: diva2:65536
Note
Addresses: Gogoll A, Univ Uppsala, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-08

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Gogoll, AdolfGrennberg, Helena

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