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Acid-catalyzed solvolytic elimination (aromatization) of allylic ethers and alcohols
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2001 (English)In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, ISSN 1472-779X, no 3, 247-251 p.Article in journal (Refereed) Published
Abstract [en]

Acid-catalyzed solvolysis of 1-methoxy-1-methyl-1,4-dihydronaphthalene (1-OMe) in 50 vol% acetonitrile in water yields exclusively the elimination product 1-methylnaphthalene (3). Neither intramolecular rearrangement giving 2-methoxy-4-methyl-1,2-dihydron

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2001. no 3, 247-251 p.
Keyword [en]
ION-MOLECULE PAIRS; MONOCYCLIC ARENES; AQUEOUS SOLVENT; LEAVING-GROUP; CARBOCATION; SUBSTITUTION; INTERMEDIATE; NUCLEOPHILES; NAPHTHALENE; METABOLISM
Identifiers
URN: urn:nbn:se:uu:diva-37641OAI: oai:DiVA.org:uu-37641DiVA: diva2:65540
Note
Addresses: Thibblin A, Univ Uppsala, Inst Chem, POB 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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