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Osmium-catalyzed asymmetric dihydroxylation of olefins by H2O2 using a biomimetic flavin-based coupled catalytic system
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2001 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, Vol. 123, no 7, 1365-1371 p.Article in journal (Refereed) Published
Abstract [en]

Selective cis-dihydroxylation of olefins with the aid of a triple catalytic system using H2O2 as the terminal oxidant has been developed. In this process Os(VI) is recycled to Os(VIII) by a coupled electron-transfer-mediator system based on N-methylmorpho

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2001. Vol. 123, no 7, 1365-1371 p.
Keyword [en]
MULTISTEP ELECTRON-TRANSFER; TERT-BUTYL HYDROPEROXIDE; VICINAL HYDROXYLATION; AEROBIC OXIDATION; HYDROGEN-PEROXIDE; MOLECULAR-OXYGEN; TETRAOXIDE; ALKENES; AMINES; DIOLS
Identifiers
URN: urn:nbn:se:uu:diva-37642OAI: oai:DiVA.org:uu-37642DiVA: diva2:65541
Note
Addresses: Backvall JE, Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Univ Uppsala, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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