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Preparation, structure, and properties of a new giant manganese oxo-alkoxide wheel, [Mn19O12(OC2H4OCH3)(14)(HOC2H4OCH3)(10)]center dot HOC2H4OCH3
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
2001 (English)In: CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, Vol. 7, no 16, 3438-3445 p.Article in journal (Refereed) Published
Abstract [en]

Alkoxides are of great interest as precursors for sol-gel processing of advanced ceramic materials, but there is very little general knowledge about the low-valent 3d-element alkoxides. The novel oxo-alkoxide, [Mn19O12(moe)(14)- (moeH)(10)] . MOEH (MOE =

Place, publisher, year, edition, pages
2001. Vol. 7, no 16, 3438-3445 p.
Keyword [en]
alkoxides; IR spectroscopy; manganese; structural elucidation; UV/Vis spectroscopy; RAY CRYSTAL-STRUCTURES; CA-MN-O; NONVOLATILE MEMORY DEVICES; BOND-VALENCE PARAMETERS; MAGNETIC-PROPERTIES; MOLECULAR-STRUCTURE; YMNO3 FILM; THIN-FILMS; MAGNETORESISTANCE;
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-37662OAI: oai:DiVA.org:uu-37662DiVA: diva2:65561
Note
Addresses: Westin LG, Uppsala Univ, Angstrom Lab, Dept Inorgan Chem, S-75121 Uppsala, Sweden. Uppsala Univ, Angstrom Lab, Dept Inorgan Chem, S-75121 Uppsala, Sweden. Stockholm Univ, Dept Struct Chem, Arrhenius Lab, S-10691 Stockholm, Sweden.Available from: 2005-10-19 Created: 2005-10-19 Last updated: 2011-01-14

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