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The mechanism of base-promoted HF elimination from 4-fluoro-4-(4 '-nitrophenyl)butan-2-one: A multiple isotope effect study including the leaving group F-18/F-19 KIE
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2001 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, Vol. 123, no 12, 2712-2718 p.Article in journal (Refereed) Published
Abstract [en]

Leaving-group fluorine as well as the primary and secondary deuterium kinetic isotope effects (KIEs)) have been determined for the base-promoted elimination of hydrogen fluoride from 4-fluoro-4-(4'-nitrophenyl)-butan-2-one in aqueous solution. The elimina

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2001. Vol. 123, no 12, 2712-2718 p.
Keyword [en]
TRANSITION-STATE; E2 MECHANISMS; ION; BORDERLINE; KETONES; E1CB
Identifiers
URN: urn:nbn:se:uu:diva-37665OAI: oai:DiVA.org:uu-37665DiVA: diva2:65564
Note
Addresses: Matsson O, Uppsala Univ, Inst Chem, POB 531, SE-75121 Uppsala, Sweden. Uppsala Univ, Inst Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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