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Competing solvolytic elimination and substitution reactions via very short-lived ion-pair intermediates
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry.
2001 (English)In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, ISSN 1472-779X, no 9, 1600-1607 p.Article in journal (Refereed) Published
Abstract [en]

The solvolysis of 9-methyl-9-(2-X-2-propyl)fluorene (X = Cl, Br, or OOCCF3) (1-X) in aqueous acetonitrile or aqueous 1,1,1-trifluoroethanol (TFE) yields the alkene, 9-methyl-9-(propen-2-yl)fluorene (2), and the alcohol, 9-methyl-9-(2-hydroxy-2-propyl)fluo

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2001. no 9, 1600-1607 p.
Keyword [en]
AQUEOUS SOLVENT; NUCLEOPHILIC-SUBSTITUTION; REACTION-MECHANISMS; CARBOCATION; DEPROTONATION; ACETONITRILE; DERIVATIVES; STEPWISE; ACID; CHLORIDE
Identifiers
URN: urn:nbn:se:uu:diva-37677OAI: oai:DiVA.org:uu-37677DiVA: diva2:65576
Note
Addresses: Thibblin A, Univ Uppsala, Inst Chem, POB 531, SE-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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